The Heck–Matsuda (HM) reaction is a powerful synthetic approach cut out for C–C bonds formation under mild conditions. We demonstrated that pyrazolyl diazonium salts are suitable reagents in this protocol, allowing us to deliver highly substituted cyclopentenols and cyclopentenamines with an excellent degree of diastereoselectivity and a control of enantioselectivity
Highly diastereoselective Heck–Matsuda reaction with pyrazolyl diazonium salts
F. Bellina;
2023-01-01
Abstract
The Heck–Matsuda (HM) reaction is a powerful synthetic approach cut out for C–C bonds formation under mild conditions. We demonstrated that pyrazolyl diazonium salts are suitable reagents in this protocol, allowing us to deliver highly substituted cyclopentenols and cyclopentenamines with an excellent degree of diastereoselectivity and a control of enantioselectivity
File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
d3nj01724a.pdf
accesso aperto
Descrizione: articolo
Tipologia:
Documento in versione editoriale
Dimensione
285.24 kB
Formato
Adobe PDF
|
285.24 kB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
