The widespread use of petroleum derivatives in industrial settings poses a challenge due to their toxicity and the difficulty of removing them from tanks, pipes, and equipment. Conventional degreasers are generally expensive, toxic, and harmful to workers’ health and the environment. In this study, an environmentally friendly biodetergent formulated from natural ingredients was produced in a pilot plant with 480 L h−1 capacity, in 250 L homogenizers, at 3500 rpm and 80 ◦C, and its performance evaluated under different operating conditions. Furthermore, the biodetergent efficiency was compared with that of commercial degreasers commonly used in industrial settings. Stability tests indicated 100% stable emulsion with 2.0% fatty alcohol and 1.0% stabilizing gum after one week of storage. In application tests, the biodetergent promoted up to 100% removal of heavy fuel oil (OCB1) and diesel from metal surfaces, both in concentrated and (1:1 v/v) diluted forms. In direct comparisons, the product performed equally or better than commercial degreasers, notably removing >95% of OCB1 in 10 min and maintaining efficiency after multiple reuse cycles. Unlike acidic or solvent-based formulations, the biodetergent did not induce corrosion on pieces or release toxic vapors when applied to heated surfaces. In summary, the developed bioproduct demonstrated industrial scalability and high efficiency, constituting a sustainable alternative for petrochemical cleaning operations in onshore and offshore environments.

Scale-Up and Application of a Green Detergent Under Industrial Conditions to Remove Petroleum Derivatives: Comparison with Commercial Degreasers

Converti, Attilio;
2026-01-01

Abstract

The widespread use of petroleum derivatives in industrial settings poses a challenge due to their toxicity and the difficulty of removing them from tanks, pipes, and equipment. Conventional degreasers are generally expensive, toxic, and harmful to workers’ health and the environment. In this study, an environmentally friendly biodetergent formulated from natural ingredients was produced in a pilot plant with 480 L h−1 capacity, in 250 L homogenizers, at 3500 rpm and 80 ◦C, and its performance evaluated under different operating conditions. Furthermore, the biodetergent efficiency was compared with that of commercial degreasers commonly used in industrial settings. Stability tests indicated 100% stable emulsion with 2.0% fatty alcohol and 1.0% stabilizing gum after one week of storage. In application tests, the biodetergent promoted up to 100% removal of heavy fuel oil (OCB1) and diesel from metal surfaces, both in concentrated and (1:1 v/v) diluted forms. In direct comparisons, the product performed equally or better than commercial degreasers, notably removing >95% of OCB1 in 10 min and maintaining efficiency after multiple reuse cycles. Unlike acidic or solvent-based formulations, the biodetergent did not induce corrosion on pieces or release toxic vapors when applied to heated surfaces. In summary, the developed bioproduct demonstrated industrial scalability and high efficiency, constituting a sustainable alternative for petrochemical cleaning operations in onshore and offshore environments.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11567/1288897
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